Lavoisier, Antoine Laurent (1743-1794)
was a French chemist, universally regarded as the founder of
modern chemistry. His contributions to the science were wide
ranging, but perhaps his most significant achievement was his
discrediting and disproof of the phlogiston theory of combustion,
which for so long had been a stumbling block to a true understanding
of chemistry.
Lavoisier was born in Paris on 26 August 1743 into a well-off
family. His mother died when he was young and he was brought up by
an aunt. He received a good education at the Collège Mazarin, where
he studied astronomy, botany, chemistry and mathematics. In 1768 he
was elected an associate chemist to the Academy of Sciences; he
eventually became its Director in 1785 and Treasurer in 1791.
Also in 1768 Lavoisier became an assistant to Baudon, one of the
farmers- general of the revenue, and later he became a full member
of the ferme générale, employed by the government as tax
collectors. He married 14-year-old Marie Paulze, daughter of a tax
farmer, in 1771 and the following year his father bought him a
title. In 1775 he was made régisseur des poudres and improved the
method of preparing saltpetre (potassium nitrate) for the
manufacture of gunpowder. A model farm he set up at Frénchines in
1778 applied scientific principles to agriculture, and he drew up
various agricultural schemes as secretary to the committee on
agriculture, to which he was appointed in 1785. Two years later he
became a member of the provincial assembly of Orléans, in which
position he initiated many improvements for the community, such as
workhouses, savings banks and canals. He was also a member of
various other committees and commissions, including that formed in
1790 to rationalize the system of weights and measures throughout
France, which ultimately led to the founding of the metric system.
During the French Revolution, Lavoisier came under suspicion
because of his membership of the ferme générale (from which he
derived a considerable income) and because of his marriage to one of
its senior executives, although his wife acted as his scientific
assistant, taking notes and even illustrating some of his books.
Jean-Paul Marat, an extremist revolutionary whose membership of the
Academy of Sciences had been blocked by Lavoisier, accused him of
imprisoning Paris and preventing air circulation because of the wall
he had built round the city in 1787. He fled from his home and
laboratory in August 1792 but was arrested in the following November
and sent for trial by the revolutionary tribunal in May 1794. At a
cursory trial Lavoisier was one of 28 unfortunates sentenced to
death. He was guillotined on 8 May 1794 and buried in a common
grave. His widow later (1805) married the US physicist Benjamin
Thompson (Count Rumford).
Among Lavoisier's early scientific work were papers of the
analysis of the mineral gypsum (hydrated calcium sulphate), on
thunder, and a refutation that water changes into 'earth' if it is
distilled repeatedly. He helped the geologist J.E. Guettard to
compile a mineralogical atlas of France.
But his most significant experiments concerned combustion. He
found that sulphur and phosphorus increased in weight when they
burned because they absorbed 'air', and reported these results in a
note he left with the Academy of Sciences in 1772. He also
discovered that when litharge (lead(II) oxide) was reduced to
metallic lead by heating with charcoal it lost weight because it had
lost 'air'. Then in 1774 Joseph Priestley produced 'dephlogisticated
air' and Lavoisier grasped the true explanation of combustion,
inventing the name oxygen (acid- maker) for the substance that
combined with caloric and formed 'oxygen gas'. He coined the word
azote for the 'non-vital air' (nitrogen) that remained after the
oxygen in normal air had been used up in combustion. In June 1783 he
published his finding that the combustion of hydrogen in oxygen
produces water, although unknown to him this fact had already been
announced by the British chemist Henry Cavendish. Lavoisier burned
various organic compounds in oxygen and determined their composition
by weighing the carbon dioxide and water produced - the first
experiments in quantitative organic analysis. Lavoisier's findings
were universally accepted after the publication of his clear and
logical Traité élémentaire de chimiein 1789, in which he listed
all the chemical elements then known (although some of these were in
fact oxides).
After establishing that organic compounds contain carbon,
hydrogen and oxygen, Lavoisier showed by weighing that matter is
conserved during fermentation as with more conventional chemical
reactions. From quantitative measurements of the changes during
breathing, he discovered the composition of respired air and showed
that carbon dioxide and water are both normal products of
respiration.
Lavoisier also made many studies outside the field of chemistry.
With Pierre Laplace he experimented with calorimetry and other
aspects of heat. He began to use solar energy for scientific
purposes as early as 1772 and observed that 'the fire of ordinary
furnaces seems less pure than that of the sun'. He anticipated later
theories about the interdependence of sequential processes in plant
and animal life forms, as described in one of his papers discovered
only many years after his death. His great contribution to science
was summed up by Joseph Lagrange who said, on the day after
Lavoisier was guillotined at the Place de la Revolution, 'It
required only a moment to sever that head, and perhaps a century
will not be sufficient to produce another like it.'
Author not available, Lavoisier, Antoine Laurent
(1743-1794). , The Hutchinson Dictionary of Scientific
Biography, 01-01-1998.
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